A novel functional MgO ∙ SiO2/polyhedral oligomeric silsesquioxane hybrids as an active filler of polypropylene

Author:

Ambrożewicz Damian1,Jakubowska Paulina1,Kloziński Arkadiusz1,Nowacka Magdalena1,Dudziec Beata2,Andrzejewska Ewa1,Jesionowski Teofil1,Marciniec Bogdan2

Affiliation:

1. Poznan University of Technology, Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, pl. M. Skłodowskiej-Curie 2, 60-965 Poznań, Poland

2. Adam Mickiewicz University, Faculty of Chemistry, Department of Organometallic Chemistry, Grunwaldzka 6, 60-780, Poland

Abstract

Abstract New organic/inorganic hybrid fillers were obtained by mechanical modification of magnesium silicate with selected polyhedral oligomeric silsesquioxane and characterized afterwards. MgO ∙ SiO2 was precipitated in a water system. The effect of chemical modification of magnesium silicate surface on their physicochemical properties was determined. Functionalization was carried out with the use of different amount of (1-(3-hydroxypropyl)dimethylsiloxy- 3,5,7,9,11,13,15-hepta(isobutyl)pentacyclo-[9.5.1.13, 9.15, 15.17, 13]octasiloxane). The polypropylene composites of 0.5, 1.0 and 1.5 wt.% modified by 10 weight parts by the mass of the filler were also produced. For the obtained polypropylene composites measurements of the tensile strength, Young’s modulus and elongation at break were performed

Publisher

Walter de Gruyter GmbH

Subject

General Chemical Engineering,General Chemistry,Biotechnology

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