The Use of Red Mud and Black Nickel Mud in Sorption of 3,5-Dichlorophenol
Author:
Kvorková Veronika1, Ivanova Tatyana2, Michálek Juraj1, Filipova Margarita3, Šefčovičová Kristína1, Soldán Maroš1ORCID
Affiliation:
1. Slovak University Of Technology In Bratislava, Faculty Of Materials Science And Technology In Trnava , Institute Of Integral Safety , Ulica Jána Bottu 2781/25, 917 24 Trnava, Slovak Republic 2. Tchaikovsky Branch “Perm National Research Polytechnic Institute” , 617764, Lenin St., 73, Tchaikovsky, Russia 3. University Of Ruse , Department Of Thermo Engineering , 7017 Ruse, Studentska Street 8 , Bulgaria
Abstract
Abstract
This article discusses the use of alternative inexpensive adsorbents – wastes from the metal production - red mud (RM) and black nickel mud (BNM) and their sorption efficiency in 3,5-dichlorophenol removal. Chlorophenols are organic compounds consisting of a benzene ring, OH groups and chlorine atoms. The effects of adsorbent dose, contact time, and temperature on sorption process were monitored. The results showed that the optimal conditions to achieve the highest sorption efficiency of 3,5-dichlorophenol were reached with the use of black nickel mud at the amount (2.0 g), sorption time (1 hour) and at increased temperature (45 °C). The sorption efficiency under these conditions was 87.99 %. With increasing sorption time, the sorption efficiency decreased and desorption occurred. The same behaviour was observed using red mud of the same amount (2.0 g) at the same temperature (45 °C); however, after 1 hour, sorption efficiency was slightly reduced (85.16 %) compared to black nickel mud. Anyway, both of used materials are suitable for the use as alternative sorbents of 3,5-dichlorophenol under suitable conditions.
Publisher
Walter de Gruyter GmbH
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