Copper (II) chloride / tetrabutylammonium bromide catalyzed oxidation of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl

Author:

Orlińska Beata1,Zawadiak Jan1

Affiliation:

1. 1Department of Chemical Organic Technology and Petrochemistry, Silesian University of Technology, Gliwice, 44-100, Poland

Abstract

AbstractThe oxidation processes of 2,6-diisopropylnaphthalene and 4,4′-diisopropylbiphenyl with oxygen in the presence of a catalyst, composed of copper(II) chloride and tetrabutylammonium bromide, were investigated. It was found that, in essence, only one isopropyl group undergoes oxidation, and obtained mixtures contained mainly peroxide, alcohol, ketone and only small amounts of hydroperoxide.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,General Chemistry

Reference19 articles.

1. http dx org;Orlińska;Appl Catal,2005

2. http dx org;Taha;Catal Lett,2009

3. http dx org;Minisci;Process Res Dev,2004

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