Mukaiyama-Michael vinylogous additions to nitroalkenes under solvent-free conditions-Reference-Cited by-同舟云学术

Mukaiyama-Michael vinylogous additions to nitroalkenes under solvent-free conditions

Published:2012-02-01 Issue:1 Volume:10 Page:47-53
ISSN:2391-5420
Container-title:Open Chemistry
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Author:

Scettri Arrigo¹,Villano Rosaria²,Manzo Patrizia¹,Acocella Maria¹

Affiliation:

1. 1University of Salerno

2. 2Reg. Baldinca

Abstract

AbstractThe first Mukaiyama-Michael vinylogous reaction of a dioxinone-derived silyl ether to nitroalkenes is reported. The conjugate addition is performed in absence of any catalyst under solvent-free conditions, proceeding with satisfactory efficiency with variously substituted nitroalkenes.Moreover, the first organocatalyzed Mukaiyama-Michael vinylogous reaction of trimethylsilyloxyfuran to nitroalkenes is described.The reaction is promoted by Brønsted acids under solvent-free conditions, taking place in moderate to good yield with variously substituted nitroalkenes..

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,General Chemistry

Link

http://link.springer.com/content/pdf/10.2478/s11532-011-0122-7.pdf

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