Re-evaluated data of dissociation constants of alendronic, pamidronic and olpadronic acids-Reference-Cited by-同舟云学术

Re-evaluated data of dissociation constants of alendronic, pamidronic and olpadronic acids

Published:2009-03-01 Issue:1 Volume:7 Page:8-13
ISSN:2391-5420
Container-title:Open Chemistry
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Author:

Boichenko Alexander¹,Markov Vadim¹,Kong Hoan¹,Matveeva Anna²,Loginova Lidia¹

Affiliation:

1. 1Department of Chemical Metrology, Kharkov V.N. Karazin National University, 61077, Kharkov, Ukraine

2. 2A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russian Federation

Abstract

AbstractThe dissociation constants of (4-amino-1-hydroxybutylidene)bisphosphonic (alendronic) acid, (3-(dimethylamino)-1-hydroxypropylidene)bisphosphonic (olpadronic) acid and (3-amino-1-hydroxypropylidene)bisphosphonic (pamidronic) acid were obtained in aqueous solutions (0.10 M KCl) and micellar solutions of cetylpyridinium chloride (0.10 M CPC) at 25.0°C. With the exception of the third dissociation constant of alendronic acid, the dissociation constants of alendronic, olpadronic and pamidronic acids in aqueous solutions matched literature data. The possibility of sodium alendronate determination by acid-base titration by NaOH solution was theoretically grounded on the basis of re-evaluated data of alendronic acid dissociation constants.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,General Chemistry

Link

http://link.springer.com/content/pdf/10.2478/s11532-008-0099-z.pdf

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