The Magnitude of the Soret Force on Colloidal Particles Measured in Microgravity

Author:

Lynch Matthew L.1,Kodger Thomas E.2,Palacio-Mancheno Paolo1,Pestak Mark W.3,Meyer William V.4

Affiliation:

1. Corporate Research Division, The Procter & Gamble Company , 8700 Mason Montgomery Rd , Mason , OH , USA 45040

2. Physical Chemistry and Soft Matter , Wageningen University & Research , Stippeneng 4 , , Wageningen , NL

3. Space Engineering Division, KBR Wyle Technology Services , 6745 Engle Rd, Suite 105 , Cleveland , OH , USA 44130

4. Universities Space Research Association (USRA) with GEARS (Glenn Engineering and Research Support), NASA Glenn Research Center , 2001 Aerospace Parkway , MS HX5-2 , Brook Park , OH , USA

Abstract

Abstract There is a broad interest in both industry and academe in understanding the time-evolution in the microstructure of colloidal gels, as such changes affect the properties of the gels including product self-life and rheology. In colloidal gels, the time-evolution results from the magnitude and the relative proportions of forces—including gravity, acting on the colloidal particles. The aim of this study was to measure the magnitude of the Soret force acting on the colloidal particles in a model gel in the microgravity on the International Space Station, as a proxy for gravitational forces in Earth-based experiments. It was found that the Soret force could be used to create an effective gravitational force of between about 10 × 10−17 N (3 milli-G) and 3 × 10−17 N (1 milli-G) on the colloidal particles, where the lower limit is set by the dominance of particle flux from Brownian forces. These results should allow mapping the behavior of colloidal gels broadly described in literature on other gels—such as polymer gels of industrial interest, where the colloidal particles are much smaller.

Publisher

Walter de Gruyter GmbH

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