Synthesis of new mesostructured cellular foams (MCFs) with NaY zeolite and their application to sorption of thorium ions

Author:

Pikus Stanisław1,Zienkiewicz-Strzałka Małgorzata2,Skibińska Małgorzata1

Affiliation:

1. Department of Crystallography, Faculty of Chemistry , Maria Curie-Skłodowska University , 3 Maria Curie-Skłodowska Square, 20-031 Lublin , Poland

2. Department of Physicochemistry of Solid Surface, Faculty of Chemistry , Maria Curie-Skłodowska University , 3 Maria Curie-Skłodowska Square, 20-031 Lublin , Poland

Abstract

Abstract The paper presents the new way of preparation of MCF foams with NaY zeolite. Significant changes in the amount of micro and mesopores in relation to the amount of NaY zeolite and 1,3,5-trimethylbenzene (TMB) added during the synthesis was observed. It suggests the possibility of controlling the micro/mesopores ratio by applying the proposed method. Environmental aspects of using new MCF/NaY foams is related to the adsorption of thorium ions (Th+4). The term of “MCF/NaY materials” refers to the general name of the material without referring to the content and state of zeolite. The obtained materials were highly effective in relation to Th+4. The adsorption capacity was greater when the number of micropores was lower. The dependence of adsorption capacity of Th+4 ions on aluminum atoms content was also confirmed.

Publisher

Walter de Gruyter GmbH

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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