The First Application of Laser-Induced Breakdown Spectroscopy: A Fast-Analytical Technique in Targeted Search for Elements in Geological Samples from Deep Boreholes in Latvia

Author:

Ganeev R. A.1,Kim V. V.1,Vorobyov D.2,Gross U.3,Ubelis A.3,Ozols D.4,Butikova J.5,Grube J.5,Sarakovskis A.5

Affiliation:

1. Laboratory of Nonlinear Optics, Institute of Astronomy at the National Science Platform FOTONIKA-LV , University of Latvia , 3 Jelgavas Str., Riga, LV – 1004 , Latvia

2. University of Latvia , 1 Jelgavas Str., Riga, LV – 1004 , Latvia

3. National Science Platform FOTONIKA-LV , University of Latvia , 4 Šķūņu Str ., Riga , , Latvia

4. Nature Conservation Agency of Latvia , 7 Baznīcas Str ., Sigulda , , Latvia

5. Institute of Solid State Physics , University of Latvia , 8 Kengaraga Str ., Riga , , Latvia

Abstract

Abstract Laser-induced breakdown spectroscopy (LIBS) provides a rapid, cost-effective, and extra-sensitive analysis of geological samples to make preliminary conclusions about the presence of valuable elements up to the trace levels in the ore. We present the first results of a highly sensitive qualitative analysis of the core samples of geological ore from two boreholes in Latvia (Staicele 1, from a depth range of 794–802 m, and Garsene (Subate) 2A, from a depth range of 1102–1103 m) using LIBS. Our measurements using this technique confirmed the high iron content and indicated traces of rare and high in-demand metals (such as Ti, V, Co, Sm, etc.) in the sample from Staicele, renewing interest in studying boreholes across Latvia. The presented pilot studies demonstrated effectiveness and unique possibility in performing a very sensitive and time-saving qualitative analysis of the composition of samples of ores from the old but still valuable borehole cores by using the LIBS method. We compare these measurements with other methods of sample analysis.

Publisher

Walter de Gruyter GmbH

Reference13 articles.

1. Kuršs, V., & Stinkule, A. (1963). Mineral Resources in Latvia (in Latvian). Riga: Zinātne.

2. Birger, A. (1979). Ore occurrence (in Russian). In Geologicheskoe stroenie i poleznie iskopaemie Latvii, J. P. Misans (ed.), (p. 448). Riga: Zinātne.

3. Birķis, A. (1979). Archaean and proterozoic groups (in Russian). In Geologicheskoe stroenie i poleznie iskopaemie Latvii, J.P. Misans (ed.), (pp. 7–17). Riga: Zinātne.

4. Karušs, J. (2018). Paleosurface and tectonic structures of the crystalline basement (in Latvian). In Latvija. Zeme, daba, tauta, valsts, I. Zarāne (ed.), (pp. 80–81). Riga: Latvijas Universitātes Akadēmiskais apgāds.

5. Vetrennikov, V. (1984). Report on the results of work on the topic: the study of iron ore formations of the Precambrian of the Latvian SSR (in Russian). Skrunda, 1, 308.

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