Combined laser and magnetic field treatment of YFeO3—containing films grown by spray-pyrolysis

Author:

Mihailov N.1,Vankov O.1,Petrova N.2,Kovacheva D.3

Affiliation:

1. 1Institute of Electronics, Bulgarian Academy of Sciences, 72, Tsarigradsko Shousse Blvd., 1784, Sofia, Bulgaria

2. 2Faculty of Chemistry, University of Sofia, 1, J. Bourchier Blvd., 1164, Sofia, Bulgaria

3. 3Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Acad. Bonchev Str., Bl. 11, 1784, Sofia, Bulgaria

Abstract

AbstractThin films (50–1200 nm) of YFeO3 were deposited on fused silica substrates by spray-pyrolysis using ethylene glycol solution of Y-Fe(III) citric complexes. The films were post deposition annealed at 750°C in static air for 2 h. Films obtained in this way were afterwards irradiated by a burst mode operated Nd-YAG laser (pulse energy 650 mJ, pulse duration 700 μs, energy density 110 mJ/cm2). The laser’s onset was synchronized with that of a magnetic field pulse of nearly square shape (magnetic induction 0.5 T, pulse duration 900 μs). The samples were placed normally to the direction of the magnetic field. The treatment does not affect the phase composition of the film but significantly increases the crystallite sizes of the phases presenting in the sample. The saturation magnetization of the films decreases as a result of the laser and magnetic field treatment and the coercive force increases by 50%.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,General Chemistry

Reference11 articles.

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2. N. Petrova, R. Todorovska, D. Todorovsky, V. Novakova and St. Groudeva-Zotova: “Yttrium—iron tartaric complexes as a potential precursor for spray—pyrolysis deposition of YFeO3 thin films”, J. Chem. Metal. Univ., (in press).

3. R. Todorovska, St. Groudeva-Zotova, D. Todorovsky, G. Tzvetkov and P. Stefanov: “Highly crystalline Y3Fe5O12 thin films by citric spray—pyrolysis”, J. Mat. Synth. Proc., Vol. 10, (2002), pp. 283–288.

4. R. Todorovska, St. Groudeva-Zotova and D. Todorovsky: “Spray-pyrolysis deposition of α-Fe2O3 thin films using iron(III) citric complexes”, Mat. Lett., Vol. 56, (2002), pp. 770–774.

5. R. Todorovska, N. Petrova and D. Todorovsky: “Spray—pyrolysis deposition of Y2O3 thin films using citric complexes as starting material”, C. R. acad. Bulg. Sci., Vol. 56, (2003), pp. 41–44.

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