Combination of methods of thermal and radiation treatment of sediments associated with PCBs – the Delor type

Author:

Fülöp Marko1,Šagátová Andrea2ORCID,Benkovský Ivan3,Prokes Karel4,Foltinova Lubica5

Affiliation:

1. ABRS Ltd. , Pomlejská 106 , Šamorín , Slovak Republic

2. Slovak University of Technology in Bratislava , Institute of Nuclear and Physical Engineering, Faculty of Electrical Engineering and Information Technology , Ilkovičova 3 , Bratislava , Slovak Republic

3. Comenius University in Bratislava , Faculty of Pharmacy , Odbojárov 10 , Bratislava , Slovak Republic

4. AGMECO LT, s.r.o. , Türkova 828 , Praha 4 , Czech Republic

5. UEBA , University of Economics in Bratislava , Dolnozemská cesta 1 , Bratislava , Slovak Republic

Abstract

Abstract An efficient method of burning polychlorinated biphenyls (PCBs) is often used to remove the environmental burden of PCBs. However, combustion produces toxic dioxins and furans (PCDD/F), so residents are increasingly rejecting this method. The heat treatment (HT) method does not burn PCBs but evaporates it from sediments. Even in this process, PCDD/Fs are formed to a lesser extent, which are destroyed by radiation processing (RP) following the HT. At the same time, the RP method degrades PCB congeners down to biphenyls, which decompose easily in the environment. A block assembly of a complex synergistic combination of equipment for methods of thermal (HT) and radiation (RP) destruction of PCBs in sediments is proposed. The efficacy of this complex was preliminarily determined at a level of 70-fold reduction in PCB concentration in sediments. To achieve a higher reduction factor in the concentration of PCBs, possible procedures for optimizing the settings of individual devices of this complex are presented.

Publisher

Walter de Gruyter GmbH

Subject

Waste Management and Disposal,Condensed Matter Physics,Safety, Risk, Reliability and Quality,Instrumentation,Nuclear Energy and Engineering,Nuclear and High Energy Physics

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