Bismuth and lead based metal organic frameworks: morphological, luminescence and Brunauer-Emmett-Teller (BET) studies-Reference-Cited by-同舟云学术

Bismuth and lead based metal organic frameworks: morphological, luminescence and Brunauer-Emmett-Teller (BET) studies

Published:2020-03-01 Issue:1 Volume:38 Page:132-137
ISSN:2083-134X
Container-title:Materials Science-Poland
language:en
Short-container-title:

Author:

Iram Shamaila¹,Imran Muhammad¹,Kanwal Farah¹,Latif Shoomaila²,Iqbal Zafar³

Affiliation:

1. Institute of Chemistry , Punjab University Lahore - Pakistan

2. Department of Chemistry , University of Lahore , Lahore , 54000, Pakistan

3. Department of Chemistry , Lahore University of Management and Sciences , Lahore , 54000, Pakistan

Abstract

Abstract Biphenyl-4,4′-dicarboxylic acid (H2BDA) was used as an organic linker to synthesize bismuth and lead based organic frameworks (1 and 2). The structural/morphological studies of these metal organic frameworks (MOFs) were done using UV-Vis, Fourier transform infrared spectroscopy (FT-IR), 1H NMR, energy dispersive spectroscopy (EDXS), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and powder X-ray diffraction method. Surface area as determined by Brunauer-Emmett-Teller (BET) studies revealed better N2 gas adsorption for MOF (1) compared to MOF (2). Both these MOFs exhibited good luminescence activity which was attributed to ligand-to-metal charge transfer transitions (LMCT).

Publisher

Walter de Gruyter GmbH

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Link

https://www.sciendo.com/pdf/10.2478/msp-2020-0021

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