Facile preparation of Co@Co3O4@Nitrogen doped carbon composite from ionic liquid as anode material for high performance lithium-ion batteries-Reference-Cited by-同舟云学术

Facile preparation of Co@Co3O4@Nitrogen doped carbon composite from ionic liquid as anode material for high performance lithium-ion batteries

Published:2020-12-01 Issue:4 Volume:38 Page:601-612
ISSN:2083-134X
Container-title:Materials Science-Poland
language:en
Short-container-title:

Author:

Xiao Mingjun¹,Meng Yanshuang¹²,Duan Chaoyu¹,Zhu Fuliang¹²,Zhang Yue³

Affiliation:

1. School of Materials Science and Engineering , Lanzhou University of Technology , Lanzhou 730050 , China

2. State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals , Lanzhou 730050 , China

3. Department of Manufacturing Engineering , Georgia Southern University , Statesboro, Georgia 30458, United States

Abstract

Abstract Co@Co3O4@Nitrogen doped carbon (Co@Co3O4@NDC) composite is synthesized by high temperature carbonization of ionic liquids followed by low temperature thermal oxidation. In the process of high temperature carbonization, cobalt ions are reduced to metallic cobalt, producing Co@Nitrogen doped carbon (Co@NDC). Co@Co3O4@NDC composite is obtained after low temperature oxidation, in which a part of the metallic cobalt is oxidized to Co3O4. The structural characterizations indicate that the composite is composed of three crystalline phases (carbon, Co and Co3O4). The results of transmission electron microscopy study show that the carbon materials not only coat the Co@Co3O4 nanoparticles, but also form carbon network that connects the Co@Co3O4 nanoparticles. This conductive carbon network is beneficial to improve the electrochemical performance of the composite. The electrochemical test results show that the Co@Co3O4@NDC composite exhibits excellent electrochemical performance, delivering the discharge capacities of 790 and 304 mAh˙g−1 after 1500 cycles at 5 C and 10 C. This excellent electrochemical performance is due to synergistic effects of Co3O4, cobalt nanoparticles embedded in carbon which has high conductivity, and nitrogen functional groups.

Publisher

Walter de Gruyter GmbH

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

Link

https://www.sciendo.com/pdf/10.2478/msp-2020-0065

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