Enhanced magnetoelastic performance in Pr/Mn-doped Laves phase (Tb,Ho)Fe2 compounds

Author:

Wang M.K.12,Liu J.J.1,Lv X.J.1,Ding Q.L.1,Li F.1,Pan Z.B.1,Xia W.X.2,Du J.2

Affiliation:

1. Faculty of Materials Science & Chemical Engineering , Ningbo University , Ningbo , China

2. Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences , Ningbo , China

Abstract

Abstract Magnetostrictive TbxHo0.8−xPr0.2Fe1.8Mn0.1 (0 ⩽ x ⩽ 0.20) alloys are prepared by arc-melting and subsequent annealing. The dopant of Pr/Mn introduced into RFe2 compounds effectively stabilizes the forming of single C15 Laves phase at ambient pressure. The easy magnetization direction (EMD) varies when Tb content increases, which is accompanied by a crystal-structural transition. EMD lies along ‹1 0 0› axis for x ⩽ 0.05, rotating to ‹1 1 1› axis for x ⩽ 0.12, with a tetragonal symmetry changing to a rhombohedral one. Magnetocrystalline-anisotropy compensation is obtained with the optimized composition of x = 0.12, shifting to the Tb-poor side in comparison to Pr/Mn-free counterpart. An enhanced effect on magnetoelastic properties is achieved in Tb0.12Ho0.68Pr0.2Fe1.8Mn0.1, which simultaneously possesses a low anisotropy and high magnetostriction performance, i.e. λS ~ 420 ppm, λ111 ~ 970 ppm, and a large low-field λa ~ 390 ppm/2 kOe, being 30 % higher than that of Pr/Mn-free compound. Combining low-cost light rare earth Pr with the lower Tb content, Tb0.12Ho0.68Pr0.2Fe1.8Mn0.1 may make it promising solution in magnetostrictive applications.

Publisher

Walter de Gruyter GmbH

Subject

Mechanical Engineering,Mechanics of Materials,Condensed Matter Physics,General Materials Science

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