Preparation of nano SnO2-Sb2O3 composite electrode by cathodic deposition for the elimination of phenol by Sonoelectrochemical oxidation

Author:

Nsaif Hind Jabbar1,Majeed Najwa Saber1,Salman Rasha H.1

Affiliation:

1. Department of Chemical Engineering, College of Engineering , University of Baghdad , Baghdad , Iraq

Abstract

Abstract The preparation of composite metal oxide to attain high efficiency in removing phenol from wastewater has a great concern. In the present study, the focus would be on adopting antimony-tin oxide coating onto graphite substrates instead of titanium; besides the effect of SbCl3 concentration on the SnO2-Sb2O3 composite would be examined. The performance of this composite electrode as the working electrode in the removal of phenol by sonoelectrochemical oxidation will be studied. The antimony-tin dioxide composite electrode was prepared by cathodic deposition with SnCl2 . 2H2O solution in a mixture of HNO3 and NaNO3, with different concentrations of SbCl3. The SnO2-Sb2O3 deposit layer’s structure and morphology were examined and the 4 g/l SbCl3 gave the more crystallized with nanoscale electrodeposition. The highest removal of phenol was 100% at a temperature of 30 oC, with a current density (CD) of 25 mA/cm2.

Publisher

Walter de Gruyter GmbH

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