Non-targeted analysis of VOCs by HS-SPME-G C/MS coupled with chemometrics as a potential tool for authentication of White Kołuda oat goose

Abstract

Abstract This study tested the possibility of using non-targeted analysis of volatile organic compounds by headspace solid-phase microextraction-gas chromatography-mass spectrometry coupled with chemometrics as a potential tool for differentiating leg meat of oat- and wheat-fed (ad libitum) White Kołuda geese. Thirty-six classification models were obtained for which the correct classification rate and classification accuracy for oatfed and wheat-fed geese were calculated based on a seven-fold cross-validation. Generally, the most advantageous method of the sample preparation was the high-temperature heat treatment version, whereas the highest correct classification rate was obtained when the chemometric analysis was carried out on the female, then male, and finally male + female variant of group comparisons (P<0.01). Furthermore, log-transformation appeared to be a slightly better data preprocessing technique in comparison to systematic ratio normalization. The obtained classification models can potentially differentiate the meat of oat-fattened from wheat-fattened White Kołuda geese.