Novel Strained Alicyclic Hydrocarbons Based on 5-Methylene-2-norbornene
-
Published:2021-09
Issue:9
Volume:61
Page:1033-1039
-
ISSN:0965-5441
-
Container-title:Petroleum Chemistry
-
language:en
-
Short-container-title:Pet. Chem.
Author:
Zarezin D. P.ORCID, Rudakova M. A.ORCID, Samoilov V. O.ORCID, Sultanova M. U.ORCID, Maximov A. L.ORCID, Bermeshev M. V.ORCID
Abstract
Abstract
The paper describes the synthesis of novel strained hydrocarbons based on a
diene of the norbornene series, namely 5-methylene-2-norbornene, using catalytic
cyclopropanation with diazomethane. The study demonstrated the possibility of
selective cyclopropanation solely along the endocyclic double bond. The
physicochemical properties of the hydrocarbons were investigated systematically.
These hydrocarbons were shown to have an advantageous combination of high
density, low freezing point, and high energy density value. The study’s findings
indicate that the compounds synthesized are promising as a component of
high-energy-density fuels for modern jet engines.
Publisher
Pleiades Publishing Ltd
Subject
Geochemistry and Petrology,Energy Engineering and Power Technology,Fuel Technology,General Chemical Engineering,General Chemistry
Reference17 articles.
1. Zhang, X., Pan, L., Wang, L., and Zou, J.-J., Chem. Eng. Sci., 2018, vol. 180, pp. 95–125. https://doi.org/10.1016/j.ces.2017.11.044 2. Chung, H.S., Chen, C.S.H., Kremer, R.A., Boulton, J.R., and
Burdette, G.W., Energy Fuels, 1999, vol. 13,
no. 3, pp. 641–649. https://doi.org/10.1021/ef980195k 3. Gringolts, M.L., Dement’ev, K.I., Kadiev, Kh.M., Maksimov, A.L.,
and Finkel’shtein, E.Sh., Petrol. Chem.,
2020, vol. 60, no. 7, pp. 751–761. 4. Azkaar, M., Vajglová, Z., Mäki-Arvela, P., Aho, A., Kumar, N.,
Palonen, H., Eränen, K., Peurla, M., Kulikov, L.A., Maximov, A.L., Mondelli, C.,
Pérez Ramírez, J., and Murzin, D.Yu., Fuel,
2020, vol. 278, no. 15, pp. 118193. https://doi.org/10.1016/j.fuel.2020.118193 5. Langlois, A. and Lebel, O., Energy
Fuels, 2010, vol. 24, pp. 5257–5263. https://doi.org/10.1021/ef100884b
Cited by
2 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
|
|