Epoxidation of Olefins in the Presence of Molybdenum Catalysts based on Porous Aromatic Frameworks-Reference-Cited by-同舟云学术

Epoxidation of Olefins in the Presence of Molybdenum Catalysts based on Porous Aromatic Frameworks

Published:2023-02-06 Issue:3 Volume:63 Page:327-335
ISSN:0965-5441
Container-title:Petroleum Chemistry
language:en
Short-container-title:Pet. Chem.

Author:

Yarchak V. A.^ORCID,Kulikov L. A.^ORCID,Maximov A. L.^ORCID,Karakhanov E. A.^ORCID

Abstract

Abstract A porous aromatic framework, namely PAF-30, was structurally modified by the introduction of complexing groups based on dipyridylamine, dipicolylamine, and acetylacetone. The materials synthesized in this manner were used as supports of molybdenum catalysts for epoxidation: PAF-30-dpa-Mo, PAF-30-dpcl-Mo, and PAF-30-AA-Mo. All the materials were examined by various analytic methods, such as IR spectroscopy, low-temperature nitrogen adsorption/desorption, X-ray photoelectron spectroscopy, elemental analysis, and transmission electron microscopy. The catalytic activity was tested in epoxidation of cyclohexene, 1-hexene, 1-octene, and styrene. The reusability of the catalysts was assessed using the case of cyclohexene epoxidation.

Publisher

Pleiades Publishing Ltd

Subject

Geochemistry and Petrology,Energy Engineering and Power Technology,Fuel Technology,General Chemical Engineering,General Chemistry

Link

https://link.springer.com/content/pdf/10.1134/S0965544123010012.pdf

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