Single-step incorporation of oh groups into the monosubstituted dodecahydro-closo-dodecaborate(2-) anion derivatives [B12H11SCN]2−, [B12H11I]2−, and [B12H11OC(O)CH3]2−

Author:

Ogarkov A. I.,Chernyavskii A. S.,Sakharov S. G.,Solntsev K. A.

Publisher

Pleiades Publishing Ltd

Subject

Materials Chemistry,Metals and Alloys,Inorganic Chemistry,General Chemical Engineering

Reference11 articles.

1. Aihara, J., Three-Dimensional Aromaticity of Polyhedral Boranes, J. Am. Chem. Soc., 1978, vol. 100, no. 11, pp. 3339–3342.

2. King, R.B., Three-Dimensional Aromaticity in Polyhedral Boranes and Related Molecules, Chem. Rev. (Washington, D. C.), 2001, vol. 101, no. 5, pp. 1119–1152.

3. Peymann, T., Knobler, C.B., and Hawthorne, M.F., A Study of the Sequential Acid-Catalyzed Hydroxylation of Dodecahydro-closo-Dodecaborate (2-), Inorg. Chem., 2000, vol. 39, no. 6, pp. 1163–1170.

4. Antsyshkina, A.S., Sadikov, G.G., Gorobinskii, L.V., et al., Random Disordering in Hydroxo Derivatives of closo-[B12H12]2− Anion: Crystal Structure of Cs2[B12H11(OH)] · CH3COOH and (PPh4)2[B12H11 (OH)] · CH3COOH · H2O, Russ. J. Inorg. Chem., 2001, vol. 46, no. 9, pp. 1323–1332.

5. Greenwood, N.N. and Morris, J.H., Synthesis of the B12H 12 2− Anion, Proc. Chem. Soc., 1963, no. 11, p. 338.

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