The World’s Largest Bauxite-Bearing Province, Fouta Djallon–Mandingo (West Africa). Part 4: a Zoning Mechanism in Laterite Bauxite-Bearing Weathering Crust

Abstract

Abstract The results of detailed exploration and year-round observations of the hydrogeological regime at large deposits, as well as special hydrochemical studies of various types of water and changes in the gas composition of the underground atmosphere in the lateritic weathering crust, of the very large bauxite-bearing province, Fouta Djallon–Mandingo, thanks to a reliable factual base, made it possible for the first time to draw a number of important conclusions about the conditions and features of zoning formation in the lateritic weathering profile. The weathering profile consists of two metasomatic columns spatially combined in plan, but vertically separated: an upper one, consisting of hydroxides and oxides of iron and aluminum, and a lower one, composed of clayey eluvium and products of hydration and decomposition of aluminosilicates—polymineral clays and kaolinite. In both columns, the processes of change begin with the same rainwater, but differ in the hydrodynamic parameters in each of the columns. Changes in the weathering profile occur in accordance with the main patterns of low-temperature infiltration metasomatism. The modern hydrogeological and gas regime in bauxite-bearing lateritic covers controls the mineralogical and geochemical zoning. Features of biological and soil processes and hydrodynamics and hydrochemistry in the weathering profile lead to a threshold nature of the change in physicochemical and biochemical conditions, providing the action of geochemical (oxidation, reduction, gley, adsorption) barriers, which is the main mechanism of zonal distribution of matter in lateritic weathering crusts.