Experimental Study of the Solubility of Natural Tantalite and Pyrochlore and Tantalum and Niobium Oxides in Hydrothermal Fluoride–Chloride Solutions

Author:

Kotova N. P.,Korzhinskaya V. S.,Shapovalov Yu. B.

Abstract

Abstract The concentration and temperature dependences of the solubility of tantalite, pyrochlore, and tantalum and niobium oxides in fluoride–chloride aqueous (mHF + mHCl) solutions at 300–550°C and 100 MPa (Co–CoO buffer) were studied experimentally. The initial concentration of HF varied from 0.01m to 2m, while the HCl concentration remained constant and was 0.5m. A comparative analysis of the equilibrium contents of Nb and Ta upon dissolution of tantalum and niobium oxides and natural tantalite and pyrochlore in fluoride, chloride, and mixed (mHF + mHCl) solutions was carried out.

Publisher

Pleiades Publishing Ltd

Subject

General Earth and Planetary Sciences,Earth and Planetary Sciences (miscellaneous)

Reference17 articles.

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