Author:
Avdeeva V. V.,Kubasov A. S.,Korolenko S. E.,Goeva L. V.,Malinina E. A.,Kuznetsov N. T.
Abstract
Abstract
Solvent-free copper(I) and thallium(I) compounds of the general formula [M2[B10H10]] have been synthesized. The compounds have been identified by IR spectroscopy and X-ray diffraction. According to X-ray diffraction data, the structures of both compounds are three-dimensional frameworks. In copper(I) complex [Cu2[B10H10]]n, the formation of three-center M–H–B bonds is observed. In thallium(I) compound Tl2[B10H10], the bond between cations and anions is ionic, which is confirmed by IR spectroscopy data. The Hirschfeld surface analysis of the boron cluster anion was performed for both compounds to identify and analyze intramolecular interactions.
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry,Materials Science (miscellaneous)
Reference45 articles.
1. N. N. Greenwood and A. Earnshaw, Chemistry of the Elements (Butterworth-Heinemann, 1997).
2. R. N. Grimes, Carboranes (Academic Press, London, 2016). https://doi.org/10.1016/B978-0-12-801894-1.09989-3
3. N. S. Hosmane, Boron Science: New Technologies and Applications (CRC Press, 2012).
4. Boron-Based Compounds: Potential and Emerging Applications in Medicine, Ed. by E. Hey-Hawkins and C. Viñas Teixidor (John. Wiley & Sons Ltd., 2018). https://doi.org/10.1002/9781119275602
5. I. B. Sivaev and V. I. Bregadze, Polyhedral Boron Hydrides in Use: Current Status and Perspectives (Nova Science Publishers, Hauppauge, 2009).
Cited by
19 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献