anti-3,7-Bis(methylbenzyl)-3,7-diaza-10-oxa[3.3.3]-propellanium diiodide monohydrate, C24H34I2N2O2 (1) and 3-benzyl-7,10-bis(methylbenzyl)-3,7,10-triaza[3.3.3]-propellanium diiodide · 0.5 CH3CN · 0.72 H2O, C32H42.9I2N3.5O0.72 (2). Moieties based on I−…H2O…I− interactions
Author:
Herbstein F. H.,Kapon M.,Reisner G. M.
Abstract
Abstract
The cations of the diazapropellanium salt 1 ([C24H32N2O2+ · 2I− · H2O]) and the triazapropellanium salt 2 ([C31H39N3
2+ · 2I− · 0.5(CH3CN) · 0.72 H2O]) have analogous configurations and conformations. Compound 2 decomposes in the MoKα
X-ray beam. Both compounds contain the known (but rather rare) I−…H2O…I− anion; previously reported manifestations of such interactions are classified in detail.
Publisher
Walter de Gruyter GmbH
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
Reference2 articles.
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2. Arnold Evidence for cryptand - Iike behavior in bibracchial lariat ether BiBLE complexes ob - tained from X ray crystallography and solution thermodynamic studies Am Chem;Echcgoyen;Soc,1987
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