Author:
Kyriakidis C. E.,Christidis P. C.,Rentzeperis P. J.,Tossidis I. A.
Abstract
Abstract
The crystal structure of the title compound, C18H13BrCl2N4OZn, has been determined from three-dimensional X-ray diffraction data. The structure is monoclinic, space group P2l/c, with a = 8.039(1), b = 19.448(2), c = 13.300(3) Å, β = 115.55(2)°, V = 1876.01 Å3 and Z = 4. The structure was solved by direct methods and refined by least-squares to a final R = 0.044 (Rw
= 0.038, Rg
= 0.041) for 1644 observed unique reflections [F
o > 5σ(F
o)]. The organic ligand acts as a tridentate chelating agent, while zinc is in a distorted trigonal bipyramidal coordination [Zn – Cl: 2.231(3)–2.246(3), Zn–N: 2.147(10)–2.149(7), Zn–O: 2.229(7) Å]. The IR and UV spectra are in accordance with the established geometrical features of the structure.
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
Cited by
10 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. SYNTHESES, CRYSTAL STRUCTURES, AND ANTIMICROBIAL ACTIVITIES OF ZINC COMPLEXES DERIVED FROM 2-AMINO-N′- (PYRIDIN-2-YLMETHYLENE)BENZOHYDRAZIDE;Journal of Structural Chemistry;2022-08
2. Synthesis, spectroscopy, thermodynamics and structure of [ZnCl2 (η3-dpktch)] (η3-dpktch = N,N,O- di-2-pyridyl ketone thiophene-2-carboxylic acid hydrazone);Journal of Coordination Chemistry;2008-09-18
3. Synthesis, characterization and molecular sensing behavior of [ZnCl2(η3-N,N,O-dpkbh)] (dpkbh=di-2-pyridyl ketone benzoyl hydrazone);Journal of Molecular Structure;2008-02
4. Monomeric molecules in the crystal structures of magnesium(II) and zinc(II) complexes with imidazole-4-carboxylate and water ligands;Journal of Coordination Chemistry;2007-03-10
5. Syntheses and Structures of N,N'-Bis(6-(2-hydroxymethyl)pyridylmethyl)piperazine, Its Two Zinc(II) Complexes and the Cadmium(II) Complex of N-(6-(2-Hydroxymethyl)pyridylmethyl)-N'-(2-pyridylmethyl)piperazine.;Acta Chemica Scandinavica;1998