Crystal structure of diaquadichlorodimethyltin · 15-crown-5-Reference-Cited by-同舟云学术

Crystal structure of diaquadichlorodimethyltin · 15-crown-5

Published:1994-07-01 Issue:7 Volume:209 Page:613-614
ISSN:2194-4946
Container-title:Zeitschrift für Kristallographie - Crystalline Materials
language:en
Short-container-title:

Author:

Amini M. M.,Zuckerman J. J.,Rheingold A. L.,Ng Seik Weng

Abstract

Abstract Dimethyltin dichloride crystallizes with 15-crown-5 from methanol as the diaqua complex, (CH3)2SnCl2 · 2H2O · 15-crown-5, C12H30Cl2O7Sn, which is monoclinic in the C2/c space group (a = 9.313(2) Å, b = 17.266(3) Å, c = 13.525(3) Å, β = 107.37(2)°; Z = 4). The tin atom occupies a distorted (trans-CH3, cis-Cl, cis-H2O octahedral site (C–Sn–C = 157.5(3)°, Sn—Cl = 2.474(1), Sn—O = 2.460(4) Å). The oxygen atoms of the polyether point away from the center of the ring and the Owater[unk]Ocrown ether distances all exceed 3.5 Å.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Link

https://www.degruyter.com/document/doi/10.1524/zkri.1994.209.7.613/pdf

Reference2 articles.

1. A new environment for water. The first authenticated example of water molecules engaged in twin, three-center hydrogen bonds. The crystal and molecular structure of the dimethyltin dichloride complex [(Me2SnCl2.H2O)2.18-crown-6]n

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