Np(V)O2+sorption on hydroxyapatite-effect of calcium and phosphate anions

Abstract

The sorption of NpO2+from aqueous solution on hydroxyapatite was studied as a function of the amount of sorbent, initial NpO2+concentration, ionic strength and pcH. The hydroxyapatite was characterized by SEM, EDS, XRD, FT-IR and ICP-MS measurements. At ionic strengths of 0.10 to 5.00 M NaClO4, the sorption increased with increased pcH to a maximum between pcH 8−8.5, then decreased as the pcH increased.The kinetics of NpO2+sorption on hydroxyapatite followed Lagergren first order kinetics. The temperature dependence of sorption was small in the range of 273−283 K, but increased more sharply at higher temperatures of 298−333 K. The heat of sorption of NpO2+was endothermic and the free energy values were exothermic indicating large, positive entropy. The activation energy for the sorption process was calculated to be 29.52±1.2 kJ/mole. The effect of calcium and phosphate on NpO2+sorption was studied as a function of concentration and pcH.