Chemical Effects of Nuclear Recoil. Alkali Bromates

Author:

Apers D. J.1,Dejehet F. G.1,Outryve D'ydewalle B. S. van1,Capron P. C.1,Jach J.2,Moorhead E.2

Affiliation:

1. Institut Interuniversitaire des Sciences Nucléaires. Centre de Physique Nucléaire. Université de Louvain (Belgique)

2. Brookhaven National Laboratory, Upton, L.I., N.Y. (USA)

Abstract

Summary An attempt is made to explain some of the discrepancies which have been observed when studying the retention of bromine in neutron irradiated bromates. In particular the influence of solvent, irradiation time and thermal annealing is investigated in potassium bromate, lithium (natural abundance) bromate and lithium (depleted in 6Li) bromate. Experiments show that a considerable amount of neutral bromine is formed upon recoil, and that the abnormal behaviour of lithium bromate is due to the consequences of 6Li(n, ɑ)T reactions. An explanation is put forward on the basis of an oxygen free intermediate recoil bromine fragment. The isotope effect on bromine recoil is confirmed.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Reference1 articles.

1. Acknowledgement Thè authors wish to thank Dr for many useful discussions and Chemical effects of nuclear transformation APEES and Trans Faraday Soc APEES and and Nucl APEES and work in course of publication;MADDOCK;Nucl Chem,1960

Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Recoil128I atoms in iodine pentoxide under /n, γ/ process;Journal of Radioanalytical and Nuclear Chemistry Letters;1986-01

2. Chemische Folgen von Kernumwandlungen in Festkörpern;Angewandte Chemie;1967-02-07

3. Recoil Effects of Neutron Reactions in Sodium Bromate;Nature;1965-02

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