Determination of Iodine, Bromine, and Chlorine in Atmospheric Samples by Neutron Activation Analysis

Author:

Duce Robert A.1,Winchester John W.1

Affiliation:

1. Departments of Geology and Geophysics and of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts

Abstract

Summary Iodine, bromine, and chlorine are determined by pile neutron activation in aqueous atmospheric samples. About 8 ml. of aqueous sample are irradiated, short-lived 38Cl, 80Br + 80mBr and 128I are separated using carriers, selective oxidation and reduction, and CCl4 extraction, and beta radioactivity is counted from solid silver halide sources. Six or seven samples per day can be analyzed with 5% accuracy.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

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