A novel synthesis of the N-13 labeled atmospheric trace gas peroxynitric acid-Reference-Cited by-同舟云学术

A novel synthesis of the N-13 labeled atmospheric trace gas peroxynitric acid

Published:2011-02-25 Issue:5 Volume:99 Page:285-292
ISSN:0033-8230
Container-title:Radiochimica Acta
language:en
Short-container-title:

Author:

Bartels-Rausch Thorsten,Ulrich Thomas¹,Huthwelker Thomas²,Ammann Markus³

Affiliation:

1. Paul Scherrer Institut, Laboratory of Radiochemistry and Environmental Che, Villigen PSI, Schweiz

2. Paul Scherrer Institut, Laboratory of Radiochemistry and, 5232 Villigen PSI, Schweiz

3. Paul Scherrer Institut, Laboratory of Radiochemistry, 5232 Villigen PSI, Schweiz

Abstract

Abstract Radioactively labeled trace gases have been successfully used to study heterogeneous chemistry of atmospheric relevance. Here we present a new synthesis of gas-phase peroxynitric acid labeled with 13N (H13NO4) to study the interaction of HNO4 with ice and snow surfaces. A yield of about 30% for HNO4 was determined. The main by-products were HNO3 and HNO2. Exposure of an ice packed bed flow tube to these species revealed that the interaction with the surface scale in the order HNO3ߙ>ߙHNO4ߙ=ߙHNO2ߙ>ߙNO2.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

Link

https://www.degruyter.com/document/doi/10.1524/ract.2011.1830/pdf

Reference28 articles.

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