Fast chemical separations and laser mass spectrometry – tools for nuclear research

Abstract

AbstractFast chemical separation procedures applied in nuclear research require dedicated experimental techniques. Rapid discontinuous separation procedures are illustrated by an example to isolate technetium from fission products. The use of a gas jet and its combination with a thermochromatographic separation and with the continuous solvent extraction technique SISAK is described and examples are given for the investigation of short-lived fission products. The potential of resonance ionization mass spectrometry (RIMS) as a highly sensitive technique using different experimental systems is outlined for ultra trace analysis of long-lived plutonium and neptunium isotopes, including isotope ratio measurements of the plutonium isotopes. In addition, the precise determination of the first ionization potentials (IP) of ten actinide elements up to einsteinium and of technetium carried out by using the photoionization threshold method and requiring sample sizes of ∼ 1012atoms is presented.