Author:
Krischner H.,Baumgartner O.,Maier H. E.,Saracoglu A. I.
Abstract
Abstract
The crystal structures of dirubidium-tetrazidozincate, Rb2Zn(N3)4, and of dithallium-tetrazidozincate, Tl2Zn(N3)4, have been determined from MoKα. single crystal X-ray diffractometer data and refined to R values of 0.073 and 0.089 respectively. Both compounds crystallize orthorhombic in space group Pca21 with Z = 4. The structures are built up of isolated Zn(N3)4 tetrahedra. The univalent cations are surrounded by nine azide groups.
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
Cited by
13 articles.
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1. Binary Polyazides of Zinc;European Journal of Inorganic Chemistry;2016-11-29
2. Azide Chemistry - An Inorganic Perspective, Part I Metal Azides: Overview, General Trends and Recent Developments;Zeitschrift für anorganische und allgemeine Chemie;2013-06
3. Crystal Structure Determination of Thallium Carbodiimide, Tl
2
NCN;Zeitschrift für anorganische und allgemeine Chemie;2007-06-25
4. Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions;Angewandte Chemie International Edition;2005-03-11
5. Polyazide Chemistry: The First Binary Group 6 Azides, Mo(N3)6, W(N3)6, [Mo(N3)7]?, and [W(N3)7]?, and the [NW(N3)4]? and [NMo(N3)4]? Ions;Angewandte Chemie;2005-03-11