Abstract
Abstract
Crystals of molybdenum hexacarbonyl are orthorhombic, with a = 12.019(2), b = 11.415(2), c = 6.488(1) Å, space group Pnma, and Z = 4. The structure has been refined to RF
= 0.025 for 1316 observed MoKα. data. The Mo(CO)6 octahedron conforms closely to idealized m3m symmetry, and the averages of chemically equivalent bond lengths are: Mo – C = 2.059(3) Å and C – O = 1.125(5) Å.
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science
Cited by
50 articles.
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