Author:
Walitzi E. M.,Saracoglu A. I.,Krischner H.
Abstract
Abstract
Dibarium-nickel-hexaazido-trihydrate crystallizes monoclinic in space group Cc, a = 10.624(4), b = 9.359(3), c = 16.275(5) Å, β = 110.72(8)°, Z = 4. The crystal structure was determined by direct methods (MoKα, 1150 observed reflections) and refined to R = 0.077. Nickel is octahedrally coordinated by six azide groups. Each of the two barium ions is surrounded by eight azide groups and two water molecules.
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science