Effects of symmetry and atomic heterogeneity on X-ray intensities – a case of hypercentric distribution*

Author:

Ghosh Sikha,Nigam G. D.

Abstract

Abstract A series expansion distribution function of the structure amplitude |F| has been used to calculate the generalised cumulative distribution function Nn (z) for a hypercentric crystal with n centres of symmetry. Modified expressions for moments have been derived considering the effect of hypercentrosymmetry for three different space groups P[unk], P2/m and Pmmm, which also take into account the effect of atomic heterogeneity in the crystal. The resultant change from the corresponding Wilson-type distribution is illustrated with the help of a hypothetical example and the effects of expansion terms have been discussed.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Effect of non-crystallographic symmetry on cumulative distribution function: case of many parallel repetitions at random;Zeitschrift für Kristallographie - Crystalline Materials;1990-02-01

2. Explicit Fourier representations of non–ideal hypercentric P.D.F.'s of E;Acta Crystallographica Section A Foundations of Crystallography;1989-03-01

3. Effect of hypersymmetry and atomic heterogeneity on cumulative distribution function;Zeitschrift für Kristallographie - Crystalline Materials;1989-02-01

4. Exact random-walk models in crystallographic statistics. II. The bicentric distribution for the space groupP\overline{1};Acta Crystallographica Section A Foundations of Crystallography;1985-01-01

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