The crystal structure of Sr-hardystonite, Sr2ZnSi2O7

Author:

Ardit Matteo,Cruciani Giuseppe1,Dondi Michele2

Affiliation:

1. University of Ferrara, Earth Science Department, Ferrara, Italien

2. Institute of Science and Technology for Ceramics (ISTEC – CNR), Faenza, Italien

Abstract

AbstractA synthetic strontium isomorph (Sr2ZnSi2O7) of the hardystonite structure (Ca2ZnSi2O7) was investigated with X-ray powder diffraction. The average structure (S.G.P-421m),a= 8.0007(1) Å,c= 5.1722(1) Å, was refined by Rietveld method and aRF2= 0.0216 was achieved using 394 independent reflections. The results show that Sr-hardystonite has a melilite-type structure with no incommensurate modulations. Its geometrical and bonding features are consistent with trends defined by the other so-called normal and modulated melilite structures.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science

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