Theoretical Investigation of Migration Pathways for Li Diffusion in h-LiTiS 2

Author:

Islam Mazharul M.1,Bredow Thomas

Affiliation:

1. Universität Bonn, Mulliken Center for Theoretical Chemistry, Bonn, Deutschland

Abstract

Abstract Lithium diffusion in highly lithiated hexagonal titanium disulphide (h-LixTiS2, x=0.88, 1.0) is investigated theoretically with periodic quantum-chemical methods. The calculated lithiation energies confirm that Li preferentially occupies the octahedral site rather than the tetrahedral site. Surprisingly, uncorrected density-functional theory (DFT) methods give better agreement with experiment for the structural parameters than the dispersion-corrected DFT-D approaches. Among the considered point defects, VLi , VTi , and Tii, Li point defects are thermodynamically preferred in h-LixTiS2. A moderate relaxation is observed for the atoms surrounding the Li defect or Ti defect site, whereas a pronounced relaxation of the nearest neighboring atoms of a Ti Frenkel defect occurs. Competing pathways for Li diffusion in h-LixTiS2 are investigated using the climbing-image Nudged-Elastic-Band (cNEB) approach. Li + ions can migrate within the crystallographic ab plane either in a direct pathway through shared edges of neighboring octahedra or via vacant tetrahedral sites. The possibility of three-dimensional Li + diffusion along the c direction is investigated via inclusion of Ti point defects and Ti Frenkel defects.

Publisher

Walter de Gruyter GmbH

Subject

Physical and Theoretical Chemistry

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