AQUA AMMONIA ELECTROLYTIC CHARACTER AND TPP COOLANT CONDUCTOMETRIC QUALITY CONTROL UNDER HIGH TEMPERATURES AND PRESSURES

Author:

Shcherbakov Vladimir Nikolayevich1,Vlaskov Grigory Andreyevich2

Affiliation:

1. Don State Technical University.

2. Rostov State University of Civil Engineering.

Abstract

To improve the operational conductometric steam quality control at the TPP, CHPP, and NPP, the technique for NaCl and NH4OH concentration in the saturated and superheated steam of the high- and supercritical pressure steam generators is developed, and a device for its implementation is offered. The error of determination in the range of the concentrations specific for the operated power plants is estimated. The equations describing the behavior of the thermodynamic dissociation constant, and limiting equivalent conductance of NH4OH in a wide range of state parameters that can be used in calculating the concentrations according to the proposed technique, as well as in water chemistry organization and management, are proposed. The assessment of the approximation error of dependences for the experimental data on the dissociation constants and limiting equivalent conductance is given.

Publisher

FSFEI HE Don State Technical University

Reference18 articles.

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2. Bushuyev, E. N. Razrabotka matematicheskoy modeli elektroprovodnosti tekhnologicheskikh vod TES. [Development of mathematical model of TPP industrial water conductivity.] Vestnik IGEU, 2009, no. 2, pp. 1–7 (in Russian).

3. Martynova, O. I., et al. Khimicheskiy kontrol na teplovykh i atomnykh elektrostantsiyakh. [Chemical control at thermal and atomic power plants.] Moscow, 1980, 320 p. (in Russian).

4. Bushuyev, E. N. Matematicheskoye modelirovaniye ionnykh ravnovesiy vodnogo teplonositelya s ispolzovaniyem izmereniya elektroprovodnosti i rN. [Mathematical simulation of water coolant ionic equilibriums through electrical-conductivity and pH measurements.] Teploenergetika, 2009, no. 7, pp. 13–18 (in Russian).

5. Shcherbakov, V. N. Issledovaniye elektrofizicheskikh svoystv vodnykh teplonositeley pri vysokikh parametrakh : dis. … kand. tekhn. nauk. [Study on electrophysical properties of water coolants at high temperatures : Cand. tech. sci. diss.] Moscow, 1980, 204 p. (in Russian).

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