Homologation of Alkyl Acetates, Alkyl Ethers, Acetals, and Ketals by Formal Insertion of Diazo Compounds into a Carbon–Carbon Bond
Author:
Affiliation:
1. Department of Applied Chemistry, Graduate School of Engineering, Osaka University
2. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University
Abstract
Funder
Core Research for Evolutional Science and Technology
Japan Society for the Promotion of Science
China Scholarship Council
Publisher
Georg Thieme Verlag KG
Subject
Organic Chemistry,Catalysis
Link
http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1523-1551.pdf
Reference34 articles.
1. Unveiling the role of boroxines in metal-free carbon–carbon homologations using diazo compounds and boronic acids
2. Rhodium(II)-catalyzed multicomponent assembly of α,α,α-trisubstituted esters via formal insertion of O–C(sp3)–C(sp2) into C–C bonds
3. Homologation of acetals of .alpha.,.beta.-unsaturated carbonyl compounds with diazoesters. Synthesis of acetals of .beta.,.gamma.-unsaturated carbonyl compounds
4. Straightforward Entry toward Highly Substituted 2,3-Dihydrobenz[b]oxepines by Ring Expansion of Benzopyryliums with Donor–Acceptor Diazo Compounds
5. Oxidative CH Bond Functionalization and Ring Expansion with TMSCHN2: A Copper(I)-Catalyzed Approach to Dibenzoxepines and Dibenzoazepines
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3. Lewis Acid‐Catalyzed Diastereoselective C−C Bond Insertion of Diazo Esters into Secondary Benzylic Halides for the Synthesis of α,β‐Diaryl‐β‐haloesters;Angewandte Chemie International Edition;2022-05-20
4. Homologation of Electron-Rich Benzyl Bromide Derivatives via Diazo C–C Bond Insertion;Journal of the American Chemical Society;2021-12-13
5. Insertion of Diazo Esters into C–F Bonds toward Diastereoselective One-Carbon Elongation of Benzylic Fluorides: Unprecedented BF3 Catalysis with C–F Bond Cleavage and Re-formation;Journal of the American Chemical Society;2021-11-12
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