Affiliation:
1. Department of Chemistry, Graduate School of Engineering Science, Osaka University
2. Graduate School of Pharmaceutical Sciences, Osaka University
Abstract
AbstractCobalt-catalyzed hydroalkynylation of alkynes, alkenes, and imines affords internal alkynes with various functional groups adjacent to the carbon–carbon triple bond moiety in an atom-economical manner. In addition, cross-coupling of in situ generated alkynylcobalt species from terminal alkynes, haloalkynes, and metal acetylides with (hetero)aromatic compounds and organic halides selectively provides various internal aryl- and alkylalkynes.1 Introduction2 Hydroalkynylation of Alkynes for 1,3-Enyne Synthesis3 Hydroalkynylation of Polar and Nonpolar Double Bonds4 Dehydrogenative Cross-Coupling Reaction Using Terminal Alkynes with Aromatic Compounds5 Cross-Coupling Reactions Using Haloalkynes as the Coupling Partners6 Cross-Coupling Reactions Using Metal Acetylides7 Conclusion
Funder
Japan Society for the Promotion of Science
Cited by
1 articles.
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