Affiliation:
1. Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China
2. Center for Excellence in Molecular Synthesis of Chinese Academy of Sciences
Abstract
AbstractOver the past decade, the combination of chiral phosphoric acid and palladium catalysis has emerged as a robust strategy to accomplish the regio- and stereoselective functionalization of inactive C–H bonds, enabling access to various types of chirality (central, planar, and axial). This review article describes the origin and advances in the asymmetric functionalization of allylic C–H, C(sp2)–H, and C(sp3)–H bonds enabled by chiral phosphoric acid and palladium combined catalysis.1 Introduction2.1 Enantioselective Allylic C–H Functionalization2.2 Enantioselective Non-allylic C(sp3)–H Functionalization2.3 Enantioselective C(sp2)–H Functionalization3 Conclusion
Funder
Ministry of Science and Technology of the People’s Republic of China
National Natural Science Foundation of China
Youth Innovation Promotion Association of the Chinese Academy of Sciences
Subject
Organic Chemistry,Catalysis
Cited by
9 articles.
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