An Efficient Route to Branched Allylsilanes through Copper-Catalyzed Allene Hydrosilylation Using Readily Available Silanes-Reference-Cited by-同舟云学术

An Efficient Route to Branched Allylsilanes through Copper-Catalyzed Allene Hydrosilylation Using Readily Available Silanes

Published:2022-04-20 Issue:13 Volume:33 Page:1255-1258
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Liu Xiao-Tao¹,Zhan Zhuang-Ping²,Chen Jun-Jia²

Affiliation:

1. Wanxiang Technology Co.

2. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University

Abstract

AbstractA CuCl-catalyzed hydrosilylation of allenes with PhSiH3 has been developed. It is the first example of using readily available cheap silane reagents to generate branched allylsilanes in copper-catalyzed allene hydrosilylation. This base-metal catalyst offered an atom-economical and efficient route to branched allylsilanes with excellent regioselectivity.

Funder

National Natural Science Foundation of China

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1829-8574.pdf

Reference4 articles.

1. Silicon-based cross-coupling reaction: an environmentally benign version

2. Organocatalytic Oxidation of Organosilanes to Silanols

3. Aerobic Copper-Catalyzed Organic Reactions

4. Conjugated Microporous Polymer as Heterogeneous Ligand for Highly Selective Oxidative Heck Reaction

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1. Selective Hydrosilylation and Hydroboration of Allenes Catalyzed by Cobalt‐Pincer Complexes;Advanced Synthesis & Catalysis;2024-05-23

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