Abstract
We disclose our synthetic studies on bilobalide, which features a Diels–Alder reaction of a cyclic anhydride to form two contiguous quaternary carbon centers, desymmetrization of a symmetric diol, and construction of a cyclic acetal under acidic conditions with inversion of configuration at an allylic position.
Funder
Japan Society for the Promotion of Science
Japan Agency for Medical Research and Development
Cited by
5 articles.
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