Abstract
The reaction mechanism for the Stevens rearrangement is one of the most controversial reaction mechanisms in organic chemistry. This account will address that controversy reviewing the experimental as well as some computational results.1 Introduction2 Evolution of the Mechanistic Knowledge2.1 Stevens (1928)2.2 Stevens (1930)2.3 Stevens (1932)2.4 Campbell (1946)2.5 Hauser (1951)2.6 Kline (1952)2.7 Lepley (1969)2.8 Baldwin (1970)3 Computational Investigations4 [2,3]-Stevens Rearrangement?5 Conclusion
Subject
Organic Chemistry,Catalysis
Cited by
20 articles.
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