Affiliation:
1. Department of Chemistry
Abstract
A nickel catalyst for the allylboration of aldehydes is reported, facilitating the preparation of homoallylic alcohols in high diastereoselectivity. The observed diastereoselectivities and NMR experiments suggest that allylation occurs through a well-defined six-membered transition state, with nickel acting as a Lewis acid.
Funder
University of Sheffield
Engineering and Physical Sciences Research Council
Subject
Organic Chemistry,Catalysis
Cited by
2 articles.
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