Abstract
Arylsilanes bearing a bulky alkoxy group on the silicon were synthesized from aryl chlorides and dialkoxydisilanes under reaction conditions utilizing SingaCycle-A3 as a palladium precatalyst and lithium benzoate in wet DMA. This report proposes the first direct and catalytic method for introducing tert-butoxy- or 1-adamantyloxysilyl groups onto various aryl moieties through the silylation reaction.
Funder
Kyoto University
Asahi Glass Foundation
Core Research for Evolutional Science and Technology
Japan Society for the Promotion of Science
Cited by
4 articles.
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