Enantiodivergent Synthesis of Both PAMPO Enantiomers Using l-Menthyl Chloroacetate and Stereomutation at P in Classical Quaternisation Reactions-Reference-Cited by-同舟云学术

Enantiodivergent Synthesis of Both PAMPO Enantiomers Using l-Menthyl Chloroacetate and Stereomutation at P in Classical Quaternisation Reactions

Published:2019-12-04 Issue:06 Volume:52 Page:909-916
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Dziuba Kamil^ORCID,Lubańska Małgorzata,Pietrusiewicz K. Michał¹

Affiliation:

1. Department of Organic Chemistry, Maria Curie-Skłodowska University

Abstract

A practical protocol for efficient synthesis of both PAMPO enantiomers as well as related functionalised P-stereogenic phosphine oxides in 1–3 steps from effectively resolved (S P)-l-menthyl o-anisyl-(phenyl)phosphinylacetate has been developed. Examples of non-stereoselective quaternisation of a tertiary phosphine by alkyl halides have been revealed.

Funder

Narodowe Centrum Nauki

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0039-1691531.pdf

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