Affiliation:
1. Graduate School of Pharmaceutical Sciences, Kyoto University
Abstract
A concise synthesis of the ACDE tetracyclic ring system of calyciphylline A-type alkaloids was investigated. The intramolecular Diels–Alder reaction of a tetrasubstituted olefin with furan enabled the construction of the ACD ring system bearing two contiguous quaternary carbons in one step, and subsequent intramolecular [3+2] cycloaddition successfully gave the E ring.
Funder
Japan Society for the Promotion of Science
Cited by
9 articles.
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