Affiliation:
1. Università degli Studi di Milano, Dipartimento di Chimica
2. Università degli Studi dell’Insubria, Dipartimento di Scienza e Alta Tecnologia
Abstract
Thanks to a highly active catalyst, the scope of the (cyclopentadienone)iron complex-promoted ‘hydrogen-borrowing’ (HB) amination has been expanded to secondary alcohols, which had previously been reported to react only in the presence of large amounts of co-catalysts. A range of cyclic and acyclic secondary alcohols were reacted with aromatic and aliphatic amines giving fair to excellent yields of the substitution products. The catalyst was also able to promote the cyclization of diols bearing a secondary alcohol group with primary amines to generate saturated N-heterocycles.
Funder
Università degli Studi di Milano
Ministero dellʼIstruzione, dellʼUniversità e della Ricerca
China Scholarship Council
Subject
Organic Chemistry,Catalysis
Cited by
15 articles.
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