Affiliation:
1. Department of Chemistry, One Shields Ave, University of California
Abstract
Insertion reactions of donor/donor carbenes have emerged from obscurity to become a versatile method for the synthesis of a variety of cyclic structures with excellent control of diastereo- and enantioselectivity. This Account describes the origin of this project as part of a natural product synthesis and the ensuing decade of reaction development that has resulted in new asymmetric methods as well as intriguing tangential observations.
Funder
Fundación de Ramon Areces
Coordenação de Aperfeicoamento de Pessoal de Nível Superior
American Chemical Society Petroleum Research Fund
National Institutes of Health
Cited by
8 articles.
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