Abstract
AbstractThe synthesis of 2-C-substituted 5-deoxyglucals from d-ribose, by using a nickel-catalyzed cross-coupling reaction of 2-iodo-5-deoxyglucals with Grignard reagents, is reported. The obtained 2-C-substituted 5-deoxyglucals were then transformed into 2-C-substituted 5-deoxyglycosides and 2-C-substituted 5-deoxynucleosides. During this work, structures published in the literature were reassigned.
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1. Recent Advances in Nickel-Catalyzed C-C Cross-Coupling;C-C Cross Couplings with 3d Base Metal Catalysts;2023