Affiliation:
1. State Key Lab of Urban Water Resource and Environment, Harbin Institute of Technology (Shenzhen)
2. School of Chemistry and Chemical Engineering, Henan Normal University
Abstract
AbstractA visible-light-induced O–H insertion reaction of diazo compounds is reported. This synthetic method, unlike conventional pathways, does not rely on transition metals, Lewis acids, or Brønsted acids; does not use any catalyst; and produces valuable α-hydroxy and α-alkoxy esters in good yields of up to 98%. The protocol exhibits a broad substrate scope and good functional-group tolerance. Notably, a gram-scale synthesis has been performed in a photochemical continuous-flow mode.
Funder
National Natural Science Foundation of China
Science and Technology Plan of Shenzhen
Natural Science Foundation of Guangdong Province
Guangdong Basic and Applied Basic Research Foundation
State Key Laboratory of Urban Water Resource and Environment
Cited by
1 articles.
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